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Contents 6 Preface 8 Chapter 1 14 Atomic Negative Ions Creation: Application in Nanocatalysis 14 Abstract 14 1. Introduction 15 2. Method of Calculation 17 3. Applications 19 3.1. Catalysis of Water to Peroxide 19 3.1.1. Exceptional Catalytic Properties of Auˉ and Pdˉ Negative Ions: H2O2 Synthesis 19 3.1.2. Enhancement of the Catalytic Property of Auˉ by Adding the Pdˉ Anion 20 3.1.3. Conclusion 23 3.2. Atomic Gold and Palladium Negative-Ion Catalysis of Light, Intermediate, and Heavy Water to Corresponding Peroxides 23 3.2.1. Introduction 23 3.2.2. Reaction Dynamics 24 3.2.3. Thermodynamics of Reactions 26 3.2.4. Concluding Remark 27 3.3. Methane Oxidation to Methanol without CO2 Emission: Catalysis by Atomic Negative Ions 28 3.3.1. Introduction 28 3.3.2. Reactions and Calculation Method 29 3.3.3. Results 31 3.3.4. Comment on Relativistic Effects 34 3.3.5. Conclusion 35 3.4. Multiple Atoms Functionalized Super Catalyst/Sensor 35 3.4.1. Introduction 35 3.4.2. Results 35 3.4.3. Concluding Remark 38 3.5. Single Atom Multifunctional Catalysts/Sensors 38 3.5.1. Introduction 38 3.5.2. Results 39 3.5.3. Concluding Remark 41 3.6. Tunable Catalysis of Water to Peroxide with Anionic, Catio

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