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Syntheses, structure, DNA docking and antimicrobial studies of copper(II) complexes with diethylenetriamine and N-bidentate ... 1 1 Introduction 1 2 Experimental section 2 2.1 Chemicals 2 2.2 Physical measurements 2 2.3 X-Ray crystallography 2 2.4 DFT calculation 2 2.5 DNA binding studies 2 2.6 Molecular docking method 2 2.7 Antimicrobial study 2 2.8 Syntheses of the mixed ligand mononuclear copper (II) complexes, 1–8 2 2.9 Synthesis of the complex [Cu(DETA)(5,6-DMPhen)](ClO4)2. CH3CN, 1: 2 2.10 Synthesis of the complex [Cu(DETA)(4,7-DMPhen)](ClO4)2, 2 3 2.11 Synthesis of the complex [Cu(DETA)(3,4,7,8-TMPhen)](BPh4)2, 3 3 2.12 Synthesis of the complex [Cu(DETA)(8-AQ)](ClO4)2, 4 3 2.13 Synthesis of the complex [Cu(DETA)(2-AMP)](ClO4)2, 5 3 2.14 Synthesis of the complex[Cu(DETA)(2-AEP)](ClO4)2, 6 3 2.15 Synthesis of the complex [Cu(DETA)(1,2-DACH)](ClO4)2, 7 3 2.16 Synthesis of the complex [Cu(DETA)(1,3-DAP)](ClO4)2, 8 4 3 Results and discussion 4 3.1 Synthetic aspects 4 3.2 Structural description 4 3.2.1 Structural description of complexes 1–8 4 3.2.2 DFT studies 5 4 Spectral characterization 6 4.1 Absorption spectra 6 4.2 Infrared spectra 6 5 DNA binding interactions 6 5.1 UV–Vis s

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