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Synthesis, characterization, DFT studies and biological assessment of palladium(II) complexes with imidazole derivatives 1 1 Introduction 1 2 Experimental 2 2.1 Chemicals 2 2.2 Preparation of complexes 2 2.3 Analytical data 2 2.3.1 Trans-dibromidobis(2-phenylimidazole)palladium(II) (1) 2 2.3.2 Trans-diiodidobis(2-phenylimidazole)palladium(II) (2) 2 2.3.3 Trans-dithiocyanatobis(2-phenylimidazole)palladium(II) (3) 2 2.3.4 Trans-dibromidobis(1,2-dimethylimidazole)palladium(II) (4) 2 2.3.5 Trans-diiodidobis(1,2-dimethylimidazole)palladium(II) (5) 2 2.3.6 Trans-dithiocyanatobis(1,2-dimethylimidazole)palladium(II) (6) 2 2.4 Instrumentation 2 2.5 X-ray structure determination 2 2.6 Computational details 2 2.7 Biological assessment 3 2.7.1 Free radical scavenging assay 3 2.7.2 Total antioxidant capacity (TAC) 3 2.7.3 Antibacterial activity 3 2.7.4 Alpha amylase inhibition test 3 3 Results and discussion 3 3.1 Synthesis and spectroscopic studies 3 3.2 Crystal structure description 4 3.3 DFT analysis 4 3.4 Biological studies 8 3.4.1 Free radical scavenging activity (FRSA) and total antioxidant capacity (TAC) 8 3.4.2 Antibacterial activity 8 3.4.3 Alpha amylase inhibition assay 9 4 Conclusion

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nonfiction