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Spin crossover in iron(II) tris(2-(2-pyridyl)benzimidazole) complex monitored by the variable temperature EXAFS by Roman Boča; Martina Vrbová; Rüdiger Werner; Wolfgang Haase is a Physics and Astronomy article available to read on EtoBox.

What is Spin crossover in iron(II) tris(2-(2-pyridyl)benzimidazole) complex monitored by the variable temperature EXAFS about?

Standard EXAFS equipment has been utilized in conducting the variable temperature experiments using the w Ž . xŽ . Ž . Fe pybzim ClO P H O sample, pybzim being a bidentate 2-2-pyridyl benzimidazole ligand. There is a jump in the 3 4 2 2 Ž . metal-ligand Fe-N distance comparable with the step in the effective magnetic moment. The distance increases from 1.95 to 2.11 A. In the transition region, the error bars are much broader than before and after this region. The transition temperature taken from the fittings is 132 K, which is about 9 K lower than that from magnetic susceptibility measurements.

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Author

Roman Boča; Martina Vrbová; Rüdiger Werner; Wolfgang Haase

Publisher

Elsevier Science; Elsevier ; Elsevier BV (ISSN 0009-2614)

Published

2000

Language

EN

Field

Physics and Astronomy (Physical Sciences)