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Polymerizations of Epoxides with Microwave Energy by Dong Zhang; James V. Crivello; James O. Stoffer is a Materials Science article available to read on EtoBox.

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## Abstract The polymerization of the bisaliphatic epoxy resin, 3,4‐epoxycyclohexylmethyl, 3,4‐epoxycyclohexylcarboxylate initiated by diaryliodonium or triarylsulfonium salts under both microwave energy and conventional thermal heating, was investigated. DSC and FTIR methods to determine the extent of polymerization were established. Some polymerization phenomena such as polymerization selectivity, polymerization temperature shift, and polymerization temperature shift by microwave power setting in microwave fields compared to thermal fields were investigated. To explain the phenomena, a theory that a new partition function existed in microwave fields was proposed with statistical thermodynamics. © 2004 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 4230–4246, 2004

Who reads Polymerizations of Epoxides with Microwave Energy?

Author

Dong Zhang; James V. Crivello; James O. Stoffer

Publisher

John Wiley and Sons; Wiley (John Wiley & Sons); John Wiley & Sons Inc.; Wiley (ISSN 0887-6266)

Published

2004

Language

EN

Field

Materials Science (Physical Sciences)