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The Annulation of 3-Alkylindoles with 1,1-Cyclopropanediesters by Michael A Kerr; Ryan G Keddy is a scholarly article available to read on EtoBox.

What is The Annulation of 3-Alkylindoles with 1,1-Cyclopropanediesters about?

A variety of indoles, all bearing a methyl group in the 3-position, underwent smooth reaction with 1,1cyelopropanediesters to yield annulated adducts in fair to excellent yield. Under kinetic control the annulation reaction was dominant, but under high temperature conditions for extended periods of time, re.arrangement occurred leading to 2,3-dialkylindoles. Hyperbaric conditions were found to be effective in sterically demanding cases.

Author

Michael A Kerr; Ryan G Keddy

Publisher

Elsevier Science; Elsevier ; Elsevier Ltd.; Elsevier BV (ISSN 0040-4039)

Published

1999

Language

EN