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The high-pressure phase of boron, {\gamma}-B28: disputes and conclusions of 5 years after discovery by Oganov, Artem R.; Solozhenko, Vladimir L.; Gatti, Carlo; Kurakevych, Oleksandr O.; Godec, Yann Le is a scholarly article available to read on EtoBox.

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{\gamma}-B28 is a recently established high-pressure phase of boron. Its structure consists of icosahedral B12 clusters and B2 dumbbells in a NaCl-type arrangement (B2){\delta}+(B12){\delta}- and displays a significant charge transfer {\delta}~0.5- 0.6. The discovery of this phase proved essential for the understanding and construction of the phase diagram of boron. {\gamma}-B28 was first experimentally obtained as a pure boron allotrope in early 2004 and its structure was discovered in 2006. This paper reviews recent results and in particular deals with the contentious issues related to the equation of state, hardness, putative isostructural phase transformation at ~40 GPa, and debates on the nature of chemical bonding in this phase. Our analysis confirms that (a) calculations based on density functional theory give an accurate description of its equation of state, (b) the reported isostructural phase transformation in {\gamma}-B28 is an artifact rather than a fact, (c) the best estimate of hardness of this phase is 50 GPa, (d) chemical bonding in this phase has a significant degree of ionicity. Apart from presenting an overview of previous results within a consistent view grounde

Author

Oganov, Artem R.; Solozhenko, Vladimir L.; Gatti, Carlo; Kurakevych, Oleksandr O.; Godec, Yann Le

Published

2011

Language

EN