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What is Paramagnetic Relaxation Enhancements Explained about?

This document discusses how cross-correlation between chemical shift anisotropy (CSA) relaxation and dipolar shielding anisotropy (DSA) relaxation, caused by the electronic Curie spin of paramagnetic metal ions, can affect measurements of paramagnetic relaxation enhancements (PREs). The CSA-DSA cross-correlation contribution has been overlooked in previous interpretations of PREs. It is shown that this effect can be large enough to compromise the assumed 1/r6 distance dependence of PREs. Under certain condi

Author

Hugo Dario Machaca Condori

Language

EN