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Polyperoxide surfactants for interface modification and compatibilization of polymer colloidal systems. I. Synthesis and properties of polyperoxide surfactants by S. Voronov; V. Tokarev; K. Oduola; Yu. Lastukhin is a Materials Science article available to read on EtoBox.

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Anhydride-containing polyperoxides were synthesized by copolymerization of 5ϪtertϪbutylperoxyϪ5ϪmethylϪ1ϪhexenϪ3Ϫyne with either maleic anhydride or its blends with styrene. The integral composition of the polyperoxides was theoretically calculated as the copolymerization process proceeded and its direct experimental evidence was obtained. In macrochain-formation behavior, the process was found to be consistent with the generally accepted regularities of binary and ternary copolymerization. By employing their polymerizational transformations, water-soluble polyperoxides exhibiting surface activity and initiating properties were obtained. In aqueous solutions, such polyperoxide surfactants form micellelike colloidal structures.

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Author

S. Voronov; V. Tokarev; K. Oduola; Yu. Lastukhin

Publisher

John Wiley and Sons; Wiley (John Wiley & Sons); John Wiley & Sons Inc.; Wiley (ISSN 0021-8995)

Published

2000

Language

EN

Field

Materials Science (Physical Sciences)