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What is Mechanism of Allylic Bromination Explained about?

In 1933, Kharasch and Mayo discovered that allylic bromination with HBr and peroxides yields an anti-Markovnikov product due to resonance stabilization of the allylic radical. N-bromosuccinimide (NBS) is utilized to generate Br2 in low concentrations, enhancing selectivity in reactions. Additionally, Bu3SnH can be activated by AIBN to produce radicals for reactions involving bromoalkyls.

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