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The study investigates the structure of MO1/2-TeO2 glasses (M = Li, Na, K, Rb, Cs, Tl) using Raman spectroscopy, revealing that the glass structure changes with varying alkali content. Low alkali content glasses feature a continuous network of TeO4 trigonal bipyramids, while higher alkali content leads to the formation of TeO3 trigonal pyramids and isolated structural units. The research also suggests a new hypothesis for the structural changes in tellurite glasses as alkali content increases.

Author

pmt28012005

Language

EN