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Can I read Modulating Structural and Electronic Properties of Rare Archimedean and Johnson-Type Mn Cages on EtoBox?
Modulating Structural and Electronic Properties of Rare Archimedean and Johnson-Type Mn Cages by Swetanshu Tandon; Friedrich W. Steuber; Amal C. Kathalikkattil; Munuswamy Venkatesan; Graeme W. Watson; Wolfgang Schmitt is a Chemistry article available to read on EtoBox.
What is Modulating Structural and Electronic Properties of Rare Archimedean and Johnson-Type Mn Cages about?
High-nuclearity Mn complexes have attracted significant scientific attention due to their fascinating magnetic properties and their relevance to bioinorganic systems and catalysis. In this work, we demonstrate how the strong binding characteristics of phosphonate ligands can be coupled with sterically hindered carboxylate groups to influence the symmetry of Mn coordination clusters. We describe the structure of two high-nuclearity Mn coordination cages, {Mn} and {Mn}, synthesized using this approach. These cages are structurally related to the truncated tetrahedral geometry and adopt rare topological features of Archimedean and Johnson-type solids. Their structural attributes distinctively influence their magnetic properties and electrocatalytic HO oxidation characteristics.
Who reads Modulating Structural and Electronic Properties of Rare Archimedean and Johnson-Type Mn Cages?
It is typically read by researchers, students, and practitioners in Chemistry.
- Author
- Swetanshu Tandon; Friedrich W. Steuber; Amal C. Kathalikkattil; Munuswamy Venkatesan; Graeme W. Watson; Wolfgang Schmitt
- Publisher
- American Chemical Society (ACS)
- Published
- 2021
- Language
- EN
- Field
- Chemistry (Physical Sciences)