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Cu(I) Trifluoromethyl Complexation Study by sylvie is a document available to read on EtoBox.
The document discusses the formation and characterization of stable, colorless salts of the [Cu(CF3)4]- ion, highlighting the elusiveness of Cu(III) complexation and the preference for trifluoromethyl oxidation. It presents a mechanism involving the formation of a copper(I) P-adduct and the subsequent collapse to product, while also examining the molecular orbital (MO) structure of the complex. The findings suggest a significant ionic character in the bonding of the complex, with implications for understand
- Author
- sylvie
- Language
- EN