Can I read Heterotrimetallic Complexes [{Pt(RNH2)2(μ-NHCOtBu)2}2M](ClO4)n (M = Mn, Co, Cu, Ni, Cd, and Zn, n = 2; M = In, n = 3), [{Pt(NH3)(μ-DACHCOtBu)(μ-NHCOtBu)}2Ni](ClO4)2, and [{Pt(RNH2)2(NHCOtBu)2}3Ag3](ClO4)3 Bridged by Amidate Ligands: A Novel Amidate−Amine Interligand Reaction During the Pt−Ni Bond Formation on EtoBox?

Heterotrimetallic Complexes [{Pt(RNH2)2(μ-NHCOtBu)2}2M](ClO4)n (M = Mn, Co, Cu, Ni, Cd, and Zn, n = 2; M = In, n = 3), [{Pt(NH3)(μ-DACHCOtBu)(μ-NHCOtBu)}2Ni](ClO4)2, and [{Pt(RNH2)2(NHCOtBu)2}3Ag3](ClO4)3 Bridged by Amidate Ligands: A Novel Amidate−Amine Interligand Reaction During the Pt−Ni Bond Formation by Wanzhi Chen; Fenghui Liu; Takuya Nishioka; Kazulo Matsumoto is a Chemistry article available to read on EtoBox.

What is Heterotrimetallic Complexes [{Pt(RNH2)2(μ-NHCOtBu)2}2M](ClO4)n (M = Mn, Co, Cu, Ni, Cd, and Zn, n = 2; M = In, n = 3), [{Pt(NH3)(μ-DACHCOtBu)(μ-NHCOtBu)}2Ni](ClO4)2, and [{Pt(RNH2)2(NHCOtBu)2}3Ag3](ClO4)3 Bridged by Amidate Ligands: A Novel Amidate−Amine Interligand Reaction During the Pt−Ni Bond Formation about?

## Abstract The neutral square‐planar complexes [Pt(NH~2~CH~2~CH~2~OCH~3~)~2~(NHCO__t__Bu)~2~], [Pt(DACH)(NHCO__t__Bu)~2~] (DACH = __trans__‐1,2‐diaminocyclohexane), and [Pt(NH~2~CH~2~CH~2~NMe~2~)(NHCO__t__Bu)~2~] have been prepared by hydrolysis of the corresponding [Pt(RNH~2~)~2~(NC__t__Bu)~2~](ClO~4~)~2~ with NaOH. Reactions of [Pt(RNH~2~)~2~(NHCO__t__Bu)~2~] with metal ions afforded Pt−M−Pt clusters [{Pt(RNH~2~)~2~(μ‐NHCO__t__Bu)~2~}~2~M](ClO~4~)~__n__~ (M = Mn, Co, Cu, Ni, Cd, Zn, and In; __n__ = 2 or 3) and [{Pt(NH~2~CH~2~CH~2~NMe~2~)(μ‐NHCO__t__Bu)~2~}~2~M](ClO~4~)~2~ (M = Co, Ni). The Pt~2~M (M = Mn, Co, Cu, Ni, Zn, and In) complexes consist of a linear Pt−M−Pt core bridged by four pivalamidate ligands. The Pt−M−Pt angles are 180° or nearly so. The central metal ions with an octahedral geometry are coordinated by four equatorial amidate oxygen atoms and two platinum atoms occupy the axial site. One of the two __t__‐BuCO group shifts to the neighboring nitrogen atom of DACH (DACH = __trans__‐1,2‐diaminocyclohexane) in the reaction of [Pt(DACH)(NHCO__t__Bu)~2~]·4H~2~O with Ni^2+^ to generate the unexpected [{Pt(NH~3~)(DACHCO__t__Bu)(μ‐NHCO__t__Bu)}~2~Ni](ClO~4~)~2~. The centr

Who reads Heterotrimetallic Complexes [{Pt(RNH2)2(μ-NHCOtBu)2}2M](ClO4)n (M = Mn, Co, Cu, Ni, Cd, and Zn, n = 2; M = In, n = 3), [{Pt(NH3)(μ-DACHCOtBu)(μ-NHCOtBu)}2Ni](ClO4)2, and [{Pt(RNH2)2(NHCOtBu)2}3Ag3](ClO4)3 Bridged by Amidate Ligands: A Novel Amidate−Amine Interligand Reaction During the Pt−Ni Bond Formation?

Author

Wanzhi Chen; Fenghui Liu; Takuya Nishioka; Kazulo Matsumoto

Publisher

John Wiley and Sons; Wiley (John Wiley & Sons); John Wiley & Sons Ltd.; Wiley (ISSN 1434-1948)

Published

2003

Language

EN

Field

Chemistry (Physical Sciences)