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Complexes of Cobalt(II) Iodide with Pyridine and Redox Active 1,2-Bis(arylimino)acenaphthene: Synthesis, Structure, Electrochemical, and Single Ion Magnet Properties by Yambulatov, Dmitriy S.; Nikolaevskii, Stanislav A.; Kiskin, Mikhail A.; Magdesieva, Tatiana V.; Levitskiy, Oleg A.; Korchagin, Denis V.; Efimov, Nikolay N.; Vasilâev, Pavel N.; Goloveshkin, Alexander S.; Sidorov, Alexey A.; Eremenko, Igor L. is a Chemistry article available to read on EtoBox.

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Complexes [(dpp-BIAN)0CoIII2]·MeCN (I) and [(Py)2CoI2] (II) were synthesized by the reaction between cobalt(II) iodide and 1,2-bis(2,6-diisopropylphenylimino)acenaphthene (dpp-BIAN) or pyridine (Py), respectively. The molecular structures of the complexes were determined by X-ray diffraction. The Co(II) ions in both compounds are in a distorted tetrahedral environment (CoN2I2). The electrochemical behavior of complex I was studied by cyclic voltammetry. Magnetochemical measurements revealed that when an external magnetic field is applied, both compounds exhibit the properties of field-induced single ion magnets.

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Author

Yambulatov, Dmitriy S.; Nikolaevskii, Stanislav A.; Kiskin, Mikhail A.; Magdesieva, Tatiana V.; Levitskiy, Oleg A.; Korchagin, Denis V.; Efimov, Nikolay N.; Vasilâev, Pavel N.; Goloveshkin, Alexander S.; Sidorov, Alexey A.; Eremenko, Igor L.

Publisher

Molecular Diversity Preservation International; MDPI AG; Multidisciplinary Digital Publishing Institute (MDPI); Berlin: Springer, 1996-; Basel: 1997-; Springer Science and Business Media LLC (ISSN 1420-3049)

Published

2020

Language

EN

Field

Chemistry (Life Sciences)