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Conventional ligand classification 456 13.11.3 Quantifying ligand electronic properties 461 13.11.3.1 Tolman electronic parameter (TEP) 461 13.11.3.2 Ligand electrochemical parameter (LEP) 464 13.11.3.3 Computed electronic parameter (CEP), molecular electrostatic potential (MESP) and metal-ligand electronic parameter (MLEP) 466 13.11.3.4 Huynh electronic parameter (HEP) 468 13.11.3.5 NMR spectroscopy of selenoureas or carbene-phosphinidene adducts and 1 J(C-H) coupling constants of azolium salts 473 13.11.4 Descriptors for ligand steric properties 475 13.11.4.1 Tolman cone angle and the bite angle 475 13.11.4.2 Percent buried volume 476 13.11.4.3 Topographic steric maps 482 13.11.5 Analysis of catalyst performance based on parameterization of ancillary ligands 484 13.11.5.1 Catalytic trends of transition metal complexes bearing monodentate phosphines 484 13.11.5.2 Parameterization of transition metal complexes bearing monodentate phosphines 486 13.11.5.3 Catalytic trends of transition metal complexes bearing diphosphines 489 13.11.5.4 Parameterization of transition metal complexes bearing diphosphines 489 13.11.5.5 Catalytic trends of transition metal complexes bearing NHC ligands

Author

Thomas Scattolin; Steven P. Nolan

Publisher

Elsevier

Published

2022

Language

EN