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Acyclic diene metathesis (ADMET) depolymerization of functionalized furan‐based polymers by T. Viswanathan; F. Gomez; K. B. Wagener is a Materials Science article available to read on EtoBox.
What is Acyclic diene metathesis (ADMET) depolymerization of functionalized furan‐based polymers about?
## Abstract Acyclic dience metathesis (ADMET) depolymerization of functionalized furan‐based polymers prepared via aqueous ring‐opening polymerization of 7‐oxanobornenes has been investigated. Results indicate that while very high molecular weight poly [exo‐__N__‐methyl‐7‐oxabicyclo [2.2.1] hept‐2,5‐diene‐2,3‐dicarboximide] can be depolymerized to oligomers with ease, poly [2,3‐dicarbomethoxy‐7‐oxabicyclo [2.2.1] hept‐2,5‐diene] is more resistant to depolymerization under similar conditions. This difference may be due to differential interaction of the carbonyls in the side chains with the metal atom of the catalyst in the proposed metallacyclobutane intermediate. ADMET depolymerization of poly [2,3‐bis (trifluoromethyl)‐7‐oxabicyclo [2.2.1] hept‐2,5‐diene] was feasible, however, the extent of depolymerization was decreased due to the use of a coordinating solvent (THF) used during the depolymerization process. © 1994 John Wiley & Sons, Inc.
Who reads Acyclic diene metathesis (ADMET) depolymerization of functionalized furan‐based polymers?
It is typically read by researchers, students, and practitioners in Materials Science.
- Author
- T. Viswanathan; F. Gomez; K. B. Wagener
- Publisher
- John Wiley and Sons; Wiley (John Wiley & Sons); John Wiley & Sons Inc.; Wiley (ISSN 0887-624X)
- Published
- 1994
- Language
- AF
- Field
- Materials Science (Physical Sciences)