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The Effect of Linker‐to‐Metal Energy Transfer on the Photooxidation Performance of an Isostructural Series of Pyrene‐Based Rare‐Earth Metal–Organic Frameworks by Victor Quezada‐Novoa; Hatem M. Titi; Francisco Yarur Villanueva; Mark W. B. Wilson; Ashlee J. Howarth is a Engineering article available to read on EtoBox.

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promising for the production of valuable chemicals, and also for the degradation of hazardous analytes. Within this realm, metal-organic frameworks (MOFs) are materials, often crystalline, comprised of metal ions, chains, or clusters interconnected by organic linkers, giving rise to highly porous structures. MOFs are excellent candidates for heterogeneous catalysis for various reactions involving organic or inorganic substrates. The catalytic performance of MOFs is highly dependent on their mass transfer capability, which relies on pore aperture size, framework topology, and defects in the crystallite surface. Mass transfer can define the rate limiting step in a catalytic process since it determines active site accessibility for the reactants, and release of products. Therefore, materials with accessible pores and channels (1D, 2D, and/or 3D) are promising as heterogeneous catalysts. Among the various subclasses of heterogeneous catalysis is photocatalysis, where photons are used to drive chemical transformations. When performing photocatalysis with MOFs, the organic linkers are typically the light harvesting structural component and can work alone as photosensitizers or together w

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Author

Victor Quezada‐Novoa; Hatem M. Titi; Francisco Yarur Villanueva; Mark W. B. Wilson; Ashlee J. Howarth

Publisher

Wiley

Published

2023

Language

EN

Field

Engineering (Physical Sciences)