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Isotope shifts and hyperfine structure in the 4s2 1S0 → 4s4p1P1 → 4s4d 1D2 transitions of stable calcium isotopes and calcium-41 by W. Nörtershäuser; N. Trautmann; K. Wendt; B.A. Bushaw is a Chemistry article available to read on EtoBox.

What is Isotope shifts and hyperfine structure in the 4s2 1S0 → 4s4p1P1 → 4s4d 1D2 transitions of stable calcium isotopes and calcium-41 about?

Isotope shifts and hyperfine structure in the 4s2 'SO -4s4p 'P, and 4s' 'So -4s4d 'D2 transitions of calcium have been measured with high-precision laser spectroscopy. Calcium atoms in an atomic beam were excited with single-frequency cw dye and titanium sapphire lasers and then photoionized with the 363.8 nm or 514.5 nm line of an argon ion laser. The resulting ions were analyzed and detected with a quadrupole mass spectrometer. Isotope shifts for all stable calcium isotopes and the radionuclide 4'Ca have been measured in both transitions. The corresponding field shift and specific mass shift coefficients as well as hyperfine structure constants for the isotopes 4',43Ca have been derived. The results are compared with previous work and values for 4'.43,46Ca in the 4s4d 'D2 state are reported for the first time.

Who reads Isotope shifts and hyperfine structure in the 4s2 1S0 → 4s4p1P1 → 4s4d 1D2 transitions of stable calcium isotopes and calcium-41?

It is typically read by researchers, students, and practitioners in Chemistry.

Author
W. Nörtershäuser; N. Trautmann; K. Wendt; B.A. Bushaw
Publisher
Elsevier Science; Elsevier ; Elsevier BV (ISSN 0584-8547)
Published
1998
Language
EN
Field
Chemistry (Physical Sciences)

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