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Determination of Transition Metal-alkyl Bond Dissociation Energies from Kinetic Measurements by Jack Halpern is a Chemistry article available to read on EtoBox.
What is Determination of Transition Metal-alkyl Bond Dissociation Energies from Kinetic Measurements about?
Transition metal-alkyl bond dissociation energies (&~\_a) may be deduced from kinetic measurements using the relation : DLnM\_-R = AHf -AHS,, where AH{ and AH?, are activation enthalpies of the homolytic bond dissociation reaction and the reverse (recombination) reaction, respectively, i.e. L,M-R z$ L,M' + R'. This has come to be one of the most widely used methods for determining such bond dissociation energies in solution. The basis, scope and limitations of the method are discussed with particular reference to the following themes : (i) determination of AH{ and AH!. I, (ii) the role and choice of free radical traps, (iii) solvent effects, (iv) magnitudes and variations of entropies of activation and (v) relation to other methods of determining transition metal-alkyl bond dissociation energies.
Who reads Determination of Transition Metal-alkyl Bond Dissociation Energies from Kinetic Measurements?
It is typically read by researchers, students, and practitioners in Chemistry.
- Author
- Jack Halpern
- Publisher
- Elsevier Science; Elsevier ; Elsevier Ltd.; Elsevier BV (ISSN 0277-5387)
- Published
- 1988
- Language
- EN
- Field
- Chemistry (Physical Sciences)