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Non-isothermal cold crystallization, melting, and moisture barrier properties of silver-loaded kaolinite filled poly(lactic ... 1 1 Introduction 2 2 Experimental 2 2.1 Materials 2 2.2 Specimen preparation 2 2.3 Characterization 3 2.3.1 Barrier properties 3 2.3.2 DSC measurements and the non-isothermal cold crystallization kinetics 3 2.3.3 Polarized optical microscopy (POM) 3 2.3.4 Melt-rheological properties 3 2.3.5 Statistical analysis 3 3 Results and discussion 3 3.1 Crystalline effect on the barrier properties of PLA/PBAT/TBT/AgKaol composite 3 3.2 The non-isothermal cold crystallization of PLA/PBAT/TBT/AgKaol composite 4 3.2.1 Avrami model 5 3.2.2 Ozawa model 5 3.2.3 Liu model 7 3.2.4 Activation energy determination by the KAS isoconversional method 8 3.3 POM analysis for melt crystallization of PLA/PBAT/TBT/AgKaol composite 9 3.4 Melt-rheological properties of PLA/PBAT/TBT/AgKaol composite 9 4 Conclusions 10 CRediT authorship contribution statement 11 Declaration of competing interest 11 Acknowledgements 11 Appendix A Supplementary data 11 References 11

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nonfiction