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Can I read Reactivity of Carbene•phosphine Dimers: Proton Affinity Revisited on EtoBox?
Reactivity of Carbene•phosphine Dimers: Proton Affinity Revisited by Min Liu; Mu Chen; Sisi Zhang; Ill Yang; Brian Buckley; Jeehiun K. Lee is a Chemistry article available to read on EtoBox.
What is Reactivity of Carbene•phosphine Dimers: Proton Affinity Revisited about?
The gas phase reactivity of __N__‐heterocyclic carbenes versus tricyclohexylphosphine (PCy~3~) is examined computationally and experimentally. New measurements indicate that dimethylimidazol‐ and 1‐ethyl‐3‐methylimidazol‐2‐ylidene are more basic than PCy~3~, in contrast to previous measurements made by us and by others. Proton‐bound dimers of the carbenes and PCy~3~ are also found to exhibit interesting reactivity involving phosphine alkylation, cyclohexene elimination, and/or ethylene elimination. This novel reactivity is further probed and discussed. Copyright © 2011 John Wiley & Sons, Ltd.
Who reads Reactivity of Carbene•phosphine Dimers: Proton Affinity Revisited?
It is typically read by researchers, students, and practitioners in Chemistry.
- Author
- Min Liu; Mu Chen; Sisi Zhang; Ill Yang; Brian Buckley; Jeehiun K. Lee
- Publisher
- John Wiley and Sons; Wiley (John Wiley & Sons); John Wiley & Sons Inc.; Wiley (ISSN 0894-3230)
- Published
- 2011
- Language
- EN
- Field
- Chemistry (Physical Sciences)