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On the Nature of Arene η6 Interactions in the Solid State and the Use of Cylindrophanes as Ligands for Sandwich Complexation of Metals with Longer-Range Interactions with the Benzene Ring by Mark Mascal; Jean-Luc Kerdelhué; Alexander J. Blake; Paul A. Cooke; Roger J. Mortimer; Simon J. Teat is a Chemistry article available to read on EtoBox.
What is On the Nature of Arene η6 Interactions in the Solid State and the Use of Cylindrophanes as Ligands for Sandwich Complexation of Metals with Longer-Range Interactions with the Benzene Ring about?
A novel mode of containment for metal ions which participate in longer-range interactions with aryl rings (Ն 2.5 A ̊) is demonstrated in the preorganized cylindrical host 1. Three equatorial sulfur atoms in 1 hold metals in a trigonal planar ligand field between two apical benzene centroids at an M-Ar distance of about 3 A ̊. Evidence of an interaction between the π electrons and the metals is gained by 1 H NMR spectroscopy of the complexes, and support for the general descrip-
Who reads On the Nature of Arene η6 Interactions in the Solid State and the Use of Cylindrophanes as Ligands for Sandwich Complexation of Metals with Longer-Range Interactions with the Benzene Ring?
It is typically read by researchers, students, and practitioners in Chemistry.
- Author
- Mark Mascal; Jean-Luc Kerdelhué; Alexander J. Blake; Paul A. Cooke; Roger J. Mortimer; Simon J. Teat
- Publisher
- John Wiley and Sons; Wiley (John Wiley & Sons); John Wiley & Sons Ltd.; Wiley (ISSN 1434-1948)
- Published
- 2000
- Language
- EN
- Field
- Chemistry (Physical Sciences)