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Can I read The Dependence of Lithium Transference Numbers on Temperature, Salt Concentration and Anion Type in Poly (Vinylidene Fluoride)–hexafluoropropylene Copolymer-based Gel Electrolytes on EtoBox?
The Dependence of Lithium Transference Numbers on Temperature, Salt Concentration and Anion Type in Poly (Vinylidene Fluoride)–hexafluoropropylene Copolymer-based Gel Electrolytes by Hongli Dai; Thomas A. Zawodzinski is a Engineering article available to read on EtoBox.
What is The Dependence of Lithium Transference Numbers on Temperature, Salt Concentration and Anion Type in Poly (Vinylidene Fluoride)–hexafluoropropylene Copolymer-based Gel Electrolytes about?
The electrophoretic NMR method was used to measure lithium transference numbers in gel electrolytes consisting of various salts in propylene carbonate-swollen poly (vinylidene fluoride) -hexafluoropropylene copolymer. We compare the concentration dependence of the lithium transference numbers obtained for a series of anions. The anions considered are CF 3 SO 3 Larger anions were generally found to result in higher lithium transference numbers. t Li in LiTf containing electrolytes decreases steadily with the salt concentration. However, in LiTFSI-containing gel electrolytes, t Li is almost invariant over a large concentration range. The results are discussed in the context of the effect of ion-ion interaction, the extent of which is dependent on the degree of anion charge delocalization.
Who reads The Dependence of Lithium Transference Numbers on Temperature, Salt Concentration and Anion Type in Poly (Vinylidene Fluoride)–hexafluoropropylene Copolymer-based Gel Electrolytes?
It is typically read by researchers, students, and practitioners in Engineering.
- Author
- Hongli Dai; Thomas A. Zawodzinski
- Publisher
- Elsevier ; Elsevier BV (ISSN 1572-6657)
- Published
- 1998
- Language
- EN
- Field
- Engineering (Physical Sciences)