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Toward the Development of Novel Poly(o-toluidine)-Based Metal Composite Materials: Structural, Optical and Electrochemical Performance by Mohammad Sohail; Rizwan Ullah; Sana Ullah Khan; Salma Bilal; Muhammad Omer; Ihsan Ullah; Adnan is a Engineering article available to read on EtoBox.

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Herein, we produced POT polymer-based tungsten (IV) oxide, (WO 2 ), cerium (IV) oxide, (CeO 2 ) and iron (III) oxide (Fe 2 O 3 ) novel composite materials by emulsion polymerization and one pot blending techniques. UV-Vis analysis confirmed various electronic transitions in π-π\* and n-π\* levels. FT-IR spectra showed the integration of reinforcement particles within the polymer matrix by the engagement of free functionalities of the polymer by the metal oxide moieties. SEM analysis described the diverse morphology (spherical, pellets, porous and rod-shaped) of the synthesized materials while the complete dispersion of reinforcement particles in the polymer matrix. Extensive cyclic voltammetry studies were done and the materials were found to be used as electroactive agents as they deliver reversible anodic and cathode peaks. The materials are less resistive toward the mobility of ions thus offering good electrical and storage properties. The prepared are proposed to be efficient in electrode and capacitors production technologies.

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Author

Mohammad Sohail; Rizwan Ullah; Sana Ullah Khan; Salma Bilal; Muhammad Omer; Ihsan Ullah; Adnan

Publisher

Springer Science and Business Media LLC

Published

2022

Language

EN

Field

Engineering (Physical Sciences)