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Pericyclic Reactions Including [2 + 2], [3 + 2], and [4 + 2] Cycloadditions by Toshiyuki Hamura is a book available to read on EtoBox.
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Arynes are highly reactive intermediates with a distorted formal triple bond. Due to the unusually low-lying LUMO, arynes exhibit the highly electrophilic character, and hence, they readily participate in pericyclic reactions, including [2+2], [3+2], and [4+2] cycloadditions. This chapter will review aryne pericyclic reactions, which is organized according to the type of cycloaddition. The rest of the article will be devoted to the reaction integration using the multiple aryne pericyclic reactions.
- Author
- Toshiyuki Hamura
- Publisher
- Elsevier
- Published
- 2022
- Language
- EN
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