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Initiation of emulsion polymerisation by gamma-irradiation. II. Rates of polymerisation in directly initiated and latex-seeded polymerisations by Allen, P. E. M. ;Burnett, G. M. ;Downer, J. M. ;Majer, J. R. is a Chemistry article available to read on EtoBox.

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## Abstract The kinetics and mechanism of emulsion polymerisations initiated by gamma‐irradiation were investigated. Styrene and methyl methacrylate emulsions polymerised either by direct irradiation or by polyvinyl acetate latices, prepared by irradiation, conformed to a SMITH‐EWART Case II mechanism. Vinyl acetate emulsions polymerised more slowly than predicted by the SMITH‐EWART theory and were probably retarded by side reactions.

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Author

Allen, P. E. M. ;Burnett, G. M. ;Downer, J. M. ;Majer, J. R.

Publisher

Wiley (John Wiley & Sons); Wiley (ISSN 0025-116X)

Published

1962

Language

EN

Field

Chemistry (Physical Sciences)