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Preface 8 Note to the Paperback Edition 16 Contents 18 PART ONE: PLANCK'S BLACK-BODY THEORY, 1894-1906: THE CLASSICAL PHASE 22 I. Planck's Route to the Black-Body Problem 24 The black-body problem 24 Planck and thermodynamics 32 Planck and the kinetic theory of gases 39 Planck on the continuum and electromagnetism 50 II. Planck's Statistical Heritage: Boltzmann on Irreversibility 59 Boltzmann's H-theorem 60 The first interpretation of the H-theorem 63 Loschmidt's paradox and the combinatorial definition of entropy 67 The conflation of "molecular" and "molar" 75 Molecular disorder 81 Epilogue: Molecular disorder and the combinatorial definition after 1896 88 III. Planck and the Electromagnetic H-Theorem, 1897-1899 93 Cavity radiation without statistics 94 The entry of statistics and natural radiation 97 Planck's "fundamental equation" 103 Entropy and irreversibility in the field 105 IV. Planck's Distribution Law and Its Derivations, 1900-1901 113 Planck's uniqueness theorem and the new distribution law 113 Recourse to combinatorials 118 Deriving the distribution law 123 The new status of the radiation constants 131 V. The Foundations of Planck's Radiation Theory, 1901-1906 135 The c

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