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What is Electronic Spectra and Vibrational Analysis about?
Electronic spectra provide information about electronic transitions in molecules. They consist of vibrational progressions that give a coarse structure and rotational transitions that provide fine structure. The Born-Oppenheimer approximation treats electronic, vibrational, and rotational motions as independent. Electronic transitions follow the Franck-Condon principle where the transition occurs much faster than nuclear relaxation, resulting in vertical transitions. This affects the intensities of vibratio
- Author
- Mahalakshmi Sahasranaman
- Language
- EN