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What is Giant pKA Shifts in Polyelectrolyte Brushes about?
This study investigates the pKA shifts in weak polyelectrolyte brushes under varying salt concentrations, revealing that high grafting densities can be explained by ideal Donnan theory, while low grafting densities require considering both Donnan and polyelectrolyte effects. The polyelectrolyte effect, which arises from neglected electrostatic correlations, remains relatively constant across salt concentrations but varies with grafting density. The findings suggest that experimentally observed pKA shifts ca
- Author
- bcpddqc
- Language
- EN