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Modular and Diverse Synthesis of Amino Acids via Asymmetric Decarboxylative Protonation of Aminomalonic Acids by Wei-Feng Zheng; Jingdan Chen; Xiaotian Qi; Zhongxing Huang is a Chemistry article available to read on EtoBox.

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are known to hold molecules together in a precise manner when working collectively 18,19 . Meanwhile, the weak nature of these forces is not expected to interrupt the primary interactions at the protonation site. However, manipulating and organizing various types of non-covalent interaction in a coordinated fashion is not an easy task. proton transfer, a pendant substituent (the anchoring group) of the olefinic intermediate could dock at the backbone of the acid in return to further affix the couple (Fig. 1d). It is also hypothesized that attractive non-covalent interactions, including π-π stacking and dispersion forces, are good candidates for these secondary interactions, as they H X NCI anchor Catalyst CO 2 H X AG \* H X a COOH \* Chiral structures H Asymmetric catalysis H H Y X X Via ion pair For example organobase Via hydrogen bonds For example decarboxylase b X Via covalent bond For example chiral metal enolate M Ligand

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Author

Wei-Feng Zheng; Jingdan Chen; Xiaotian Qi; Zhongxing Huang

Publisher

Springer Science and Business Media LLC

Published

2023

Field

Chemistry (Physical Sciences)