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μ-Oxalato-κ2O1,O2:κ2O1′,O2′-bis[(η5-pentamethylcyclopentadienyl)(trifluoromethanesulfonato-κO)rhodium(III)] by Govindaswamy, Padavattan ;Süss-Fink, Georg ;Therrien, Bruno is a Chemistry article available to read on EtoBox.

What is μ-Oxalato-κ2O1,O2:κ2O1′,O2′-bis[(η5-pentamethylcyclopentadienyl)(trifluoromethanesulfonato-κO)rhodium(III)] about?

In the title dinuclear rhodium complex, [(- the terminal trifluoromethanesulfonate ligands adopt a trans configuration with respect to each other and the RhÁ Á ÁRh distances range from 5.5157 (8) to 5.5389 (6) A ̊. There are two and a half molecules within the asymmetric unit, one of the molecules lying on an inversion centre. Interestingly, in one molecule, the S-O bond of a coordinated O atom is shorter than the two S-O bonds of the noncoordinated O atoms, and the corresponding Rh-O distance is significantly longer than the other M-O distances.

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Author

Govindaswamy, Padavattan ;Süss-Fink, Georg ;Therrien, Bruno

Publisher

International Union of Crystallography; Chester UK: International Union of Crystallography, 2001-2014.; [S.l.]: Wiley-Blackwell; [Chester]: 2008-; International Union of Crystallography (IUCr) (ISSN 1600-5368)

Published

2007

Language

EN

Field

Chemistry (Physical Sciences)