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This document reports on research into addition and solvolysis reactions involving norbornane systems. Acid-catalyzed additions of acids like acetic acid to compounds like endo-dihydrodicyclopentadiene led predominantly to products with rearranged, exo ring skeletons and exo substituents. Solvolysis of related compounds in methanol also gave mostly exo products. These results were initially thought to be consistent with reactions proceeding through a single intermediate like a non-classical carbocation that

Author

manuel querol

Language

EN