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What is Synthesis of Diazo-Functionalized Furans about?

This article presents methods for the chemoselective and regioselective synthesis of diazo-functionalized 2-methylene-2,3-dihydrofurans and trisubstituted furans using enynones and diazo carbonyl compounds. The reactions are facilitated by a combination of AgSbF6 and DBU under controlled conditions, achieving high diastereoselectivity and Z-selectivity. Additionally, the study explores the application of these compounds in constructing complex organic frameworks for the first time.

Author

larahdiasl02

Language

EN