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A novel dinuclear nickel (II) complex: spectroscopic and magnetic studies by Subrata Kumar Dey; M.Salah El Fallah; Joan Ribas; T. Matsushita; V. Gramlich; Samiran Mitra is a scholarly article available to read on EtoBox.

What is A novel dinuclear nickel (II) complex: spectroscopic and magnetic studies about?

complex has been synthesized and characterized. Characterization based on elemental analyses, infrared and electronic spectra, thermal studies, variable temperature magnetic susceptibility measurement and crystal structure analysis. The complex crystallizes in the monoclinic system, space group P 2ð1Þ=n with a 1⁄4 16:818ð11Þ, b 1⁄4 20:386ð11Þ, c 1⁄4 20:589ð13Þ, b 1⁄4 90:94ð5Þ and Z 1⁄4 8. The complex shows di-l-trichloroacetate bridging with concatenated methanol molecule hydrogen bonded with another trichloroacetate. Magnetic susceptibility measurements of complex 1 reveal an antiferromagnetic intra-dimer interaction with the J value deduced from the spin Hamiltonian H 1⁄4 ÀJ S 1 S 2 .

Author

Subrata Kumar Dey; M.Salah El Fallah; Joan Ribas; T. Matsushita; V. Gramlich; Samiran Mitra

Publisher

Elsevier Science; Elsevier ; Elsevier BV (ISSN 0020-1693)

Published

2004

Language

EN