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Multisite Solid Catalyst for Cascade Reactions: The Direct Synthesis of Benzodiazepines from Nitro Compounds by Maria J. Climent; Avelino Corma; Sara Iborra; Laura L. Santos is a Chemistry article available to read on EtoBox.

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## Abstract Substituted 1,5‐benzodiazepines are selectively synthesized in one pot from substituted nitroaromatics and ketones. The reaction is performed in the presence of hydrogen and in the absence of solvent by using a bifunctional solid catalyst with a chemoselective hydrogenation functional group capable of reducing the nitro group to a diamino group and an acid functional group, which catalyzes the cyclocondensation of the amino group with the ketone.

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Author

Maria J. Climent; Avelino Corma; Sara Iborra; Laura L. Santos

Publisher

John Wiley and Sons; Wiley (John Wiley & Sons); John Wiley & Sons Ltd.; Wiley (ISSN 0947-6539)

Published

2009

Language

EN

Field

Chemistry (Physical Sciences)