Can I read Synthesis of tritium-labelled cembrene-A on EtoBox?

Synthesis of tritium-labelled cembrene-A by Ambarish K. Singh; Glenn D. Prestwich is a Chemistry article available to read on EtoBox.

What is Synthesis of tritium-labelled cembrene-A about?

Commiphora s a p ( 3 1 , s o f t c o r a l s ( 4 1 , termite s o l d i e r s (5-8), t e r m i t e workers (9-101, and a n t s (11). Neither t h e b i o s y n t h e s i s of cembrene-A (presumably from g e r a n y l g e r a n y l pyrophosphate) nor i t s conversion i n t o any simple epoxide, d i o l , e t h e r , l a c t o n e , o r complex p o l y c y c l i c s t r u c t u r e has y e t been demonstrated i n v i v o or -i n v i t r o . b i o g e n e s i s of cembrenoids has been t h e absence of a r a d i o l a b e l l e d isotopomer f o r metabolic s t u d i e s . We r e p o r t h e r e i n a mild and s e l e c t i v e process f o r i n t r o d u c i n g a high s p e c i f i c a c t i v i t y t r i t i u m l a b e l a t C-16 ( t h e methylidene carbon). The method h a s g e n e r a l a p p l i c a b i l i t y t o t h e l a b e l l i n g of p o l y o l e f i n i c t e r p e n e hydrocarbons b e a r i n g a n i s o p r o p e n y l s i d e chain.

Who reads Synthesis of tritium-labelled cembrene-A?

Author

Ambarish K. Singh; Glenn D. Prestwich

Publisher

John Wiley and Sons; Wiley (John Wiley & Sons); John Wiley & Sons Inc.; Wiley (ISSN 0022-2135)

Published

1986

Language

EN

Field

Chemistry (Life Sciences)