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Mechanisms of Separation Using the Ternary Mixture Dichloromethane—ethanol—water in High-performance Liquid Chromatography by J.H.M. Van Den Berg; J. Milley; N. Vonk; R.S. Deelder is a Chemistry article available to read on EtoBox.

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The mechanisms of separation using the ternary system dichloromethaneethanol-water in high-performance liquid chromatography were investigated. The use of an eluent saturated with water results in a separation based on partition of the component between a polar stationary phase, held in the pores of the porous support, and an apolar mobile phase percolating through the packed bed. Selective separations according to an adsorption mechanism are obtained by using an eluent partially saturated with water, corresponding to a point outside the r$scibility gap of the three solvents.

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Author

J.H.M. Van Den Berg; J. Milley; N. Vonk; R.S. Deelder

Publisher

Elsevier Science; Elsevier ; Elsevier BV (ISSN 1873-3778)

Published

1977

Language

EN

Field

Chemistry (Physical Sciences)