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Interaction between meso-Phenyl-Substituted Porphirinioids and Carboxylic Acids, and a Thermal Analysis of Their Cationic Salts by Likhonina, A. E.; Krestâyaninov, M. A.; Morshnev, F. K.; Kritskii, E. L.; Kudayarova, T. V.; Berezin, D. B. is a Chemistry article available to read on EtoBox.
What is Interaction between meso-Phenyl-Substituted Porphirinioids and Carboxylic Acids, and a Thermal Analysis of Their Cationic Salts about?
Thermogravimetry and quantum chemistry, including NBO analysis, are used to study the thermal stability and NH acidity of single and double protonated forms of tetrapyrrole macroheterocyclic ligands (porphyrins, their inverted and N-substituted analogs, and corroles). The temperature ranges of the destruction of porphyrinium acetates and trifluoroacetates, the enthalpies of evaporation of acid molecules from the crystalline phase, and the composition of cationic salts are calculated. The structures of protonated forms of macrocycles are optimized. The energies of porphyrin-acid interaction and the values of charge transfer during the formation of bonds are calculated.
Who reads Interaction between meso-Phenyl-Substituted Porphirinioids and Carboxylic Acids, and a Thermal Analysis of Their Cationic Salts?
It is typically read by researchers, students, and practitioners in Chemistry.
- Author
- Likhonina, A. E.; Krestâyaninov, M. A.; Morshnev, F. K.; Kritskii, E. L.; Kudayarova, T. V.; Berezin, D. B.
- Publisher
- International Academic Publishing Co (Nauka/Interperiodica); Pleiades Publishing; Pleiades Publishing Ltd (ISSN 0036-0244)
- Published
- 2020
- Language
- EN
- Field
- Chemistry (Physical Sciences)