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Can I read Graft Copolymerization of 2‐Methacryloyloxyethyl Phosphorylcholine to Cellulose in Homogeneous Media Using Atom Transfer Radical Polymerization for Providing New Hemocompatible Coating Materials on EtoBox?
Graft Copolymerization of 2‐Methacryloyloxyethyl Phosphorylcholine to Cellulose in Homogeneous Media Using Atom Transfer Radical Polymerization for Providing New Hemocompatible Coating Materials by Lifeng Yan; Kazuhiko Ishihara is a Materials Science article available to read on EtoBox.
What is Graft Copolymerization of 2‐Methacryloyloxyethyl Phosphorylcholine to Cellulose in Homogeneous Media Using Atom Transfer Radical Polymerization for Providing New Hemocompatible Coating Materials about?
## Abstract To develop new hemopurification systems based on cellulose membrane, we synthesized a graft copolymer of cellulose with poly(2‐methacryloyloxyethyl phosphorylcholine) (MPC) by a metal‐catalyzed atom transfer radical polymerization process in homogeneous media. First, cellulose was dissolved in a DMAc/LiCl solution system, and it reacted with 2‐bromoisobutyloyl bromide to produce macroinitiator (cell‐BiB). Then, MPC was polymerized to the cellulose backbone in a homogeneous DMSO/methanol mixture solution in the presence of cell‐BiB. Characterization with FT‐IR, NMR, and GPC measurements showed that there obtained a graft copolymer of cellulose backbone and poly(MPC) side chains (cell‐PMPC) with well‐defined structure, indicating a controlled/“living” radical polymerization. The proteins adsorption studies showed that cellulose membranes modified by the as‐prepared cell‐PMPC owns good protein adsorption resistance. © 2008 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 46: 3306–3313, 2008
Who reads Graft Copolymerization of 2‐Methacryloyloxyethyl Phosphorylcholine to Cellulose in Homogeneous Media Using Atom Transfer Radical Polymerization for Providing New Hemocompatible Coating Materials?
It is typically read by researchers, students, and practitioners in Materials Science.
- Author
- Lifeng Yan; Kazuhiko Ishihara
- Publisher
- John Wiley and Sons; Wiley (John Wiley & Sons); John Wiley & Sons Inc.; Wiley (ISSN 0887-624X)
- Published
- 2008
- Language
- EN
- Field
- Materials Science (Physical Sciences)