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Synthesis, structure and magnetism of M(hfac)2 complexes with spin labelled amides by Eugene V Tretyakov; Olga V Koreneva; Galina V Romanenko; Yu G Shvedenkov; Victor I Ovcharenko is a Chemistry article available to read on EtoBox.
What is Synthesis, structure and magnetism of M(hfac)2 complexes with spin labelled amides about?
An effective method for the synthesis of 4,4,5,5-tetramethyl-3-oxide-1-oxyl-4,5-dihydro-1H -imidazole-2-carbonitrile (1) has been found. 4,4,5,5-Tetramethyl-3-oxide-1-oxyl-4,5-dihydro-1H -imidazole-2-carboxylic (8) and 4,4,5,5-tetramethyl-1-oxyl-4,5-dihydro-1H -imidazole-2-carboxylic (9) acid amides have been synthesized and structurally characterized using 1 as the starting compound. Reactions of Mn(hfac) 2 , Cu(hfac) 2 and Co(hfac) 2 with 8 and 9 lead to heterospin compounds tending to form in solid bi-or tetranuclear complexes due to intermolecular H-bonding between the peripheral NH 2 groups and the coordinated carbonyl oxygen atoms.
Who reads Synthesis, structure and magnetism of M(hfac)2 complexes with spin labelled amides?
It is typically read by researchers, students, and practitioners in Chemistry.
- Author
- Eugene V Tretyakov; Olga V Koreneva; Galina V Romanenko; Yu G Shvedenkov; Victor I Ovcharenko
- Publisher
- Elsevier Science; Elsevier ; Elsevier Ltd.; Elsevier BV (ISSN 0277-5387)
- Published
- 2004
- Language
- EN
- Field
- Chemistry (Physical Sciences)