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Diastereoselective addition of allylic reagents to chiral α-ketoimides derived from Oppolzer's sultam by Katarzyna Kiegiel; Janusz Jurczak is a Chemistry article available to read on EtoBox.

What is Diastereoselective addition of allylic reagents to chiral α-ketoimides derived from Oppolzer's sultam about?

Additions of allylmagnesium chloride and allyl bromide in the presence of zinc dust to N-methyl-and N-phenylglyoxyloyl-(2R)-bomane-10,2-sultam and the Lewis acid-mediated additions of allyltrimethy|silane to these chiral ct-ketoimides were studied. High diastereoselection in these reactions was observed, and in the case o f the allyltrimethylsilane/TiCl4 additions, a change of direction of asymmetric induction was found.

Who reads Diastereoselective addition of allylic reagents to chiral α-ketoimides derived from Oppolzer's sultam?

It is typically read by researchers, students, and practitioners in Chemistry.

Author
Katarzyna Kiegiel; Janusz Jurczak
Publisher
Elsevier Science; Elsevier ; Elsevier Ltd.; Elsevier BV (ISSN 0040-4039)
Published
1999
Language
EN
Field
Chemistry (Physical Sciences)

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