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Can I read 2′-fluoromaltose: Synthesis and properties of 4-O-(2-deoxy-2-fluoro-α-d-glucopyranosyl)-d-glucopyranose, and the crystal structure of 2,3-di-O-acetyl-1,6-anhydro-4-O-(3,4-tri-O-acetyl-2-deoxy-2-fluoro-α-d-glucopyranosyl)-β-d- glucopyranose on EtoBox?
2′-fluoromaltose: Synthesis and properties of 4-O-(2-deoxy-2-fluoro-α-d-glucopyranosyl)-d-glucopyranose, and the crystal structure of 2,3-di-O-acetyl-1,6-anhydro-4-O-(3,4-tri-O-acetyl-2-deoxy-2-fluoro-α-d-glucopyranosyl)-β-d- glucopyranose by Judith G. Shelling; David Dolphin; Peter Wirz; Roger E. Cobbledick; Frederick W.B. Einstein is a Biochemistry, Genetics and Molecular Biology article available to read on EtoBox.
What is 2′-fluoromaltose: Synthesis and properties of 4-O-(2-deoxy-2-fluoro-α-d-glucopyranosyl)-d-glucopyranose, and the crystal structure of 2,3-di-O-acetyl-1,6-anhydro-4-O-(3,4-tri-O-acetyl-2-deoxy-2-fluoro-α-d-glucopyranosyl)-β-d- glucopyranose about?
Coupling of 3,4,6-tri-O-acetyl-2-deoxy-2-fluoro-a-D-glucopyranosyl bromide and 3,4,6-tri-0-acetyl-2-deoxy-2-fluoro-c~-D-galactopyranosyl bromide with 2,3-di-0-acetyl-1,6-anhydro-p-D-glucose, under Koenigs-Knorr reaction conditions gave, in both instances, only the corresponding cu-(l-4)-linked disaccharides. In the first case, the linkage was verified by 'H-and "F-n.m.r., and by X-ray crystallographic analysis of 2,3-di-O-acetyl-l,6-anhydro-4-0-(3,4,6-tri-O-acetyl-2-deoxy-2-fluoro-cY-D-glucopyranosyl)-P-D-glucopyranose. Deprotection of this disaccharide gave 2'-deoxy-2'-fluoromaltose. Maltose and its fluorinated analogue displayed similar 'H-and 13C-n.m.r. spectra and optical rotations, indicating that these two sugars are isomorphous in solution and suggesting that 2'-deoxy-2'fluoromaltose might be a suitable substrate for studies of a-glycosidases.
Who reads 2′-fluoromaltose: Synthesis and properties of 4-O-(2-deoxy-2-fluoro-α-d-glucopyranosyl)-d-glucopyranose, and the crystal structure of 2,3-di-O-acetyl-1,6-anhydro-4-O-(3,4-tri-O-acetyl-2-deoxy-2-fluoro-α-d-glucopyranosyl)-β-d- glucopyranose?
It is typically read by researchers, students, and practitioners in Biochemistry, Genetics and Molecular Biology.
- Author
- Judith G. Shelling; David Dolphin; Peter Wirz; Roger E. Cobbledick; Frederick W.B. Einstein
- Publisher
- Elsevier Science; Elsevier ; Elsevier Ltd.; Elsevier BV (ISSN 0008-6215)
- Published
- 1984
- Language
- EN
- Field
- Biochemistry, Genetics and Molecular Biology (Life Sciences)