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X-ray diffraction study of strain-induced crystallization of hydrogenated nitrile-butadiene rubbers: Effect of crosslink density by Femina, Giuseppe (author);de Ballesteros, Odda Ruiz (author);Urciuoli, Gaia (author);van Duin, Martin (author);Gögelein, Christoph (author);Tammaro, Daniele (author);Sotta, Paul (author);Auriemma, Finizia (author) is a Materials Science article available to read on EtoBox.

What is X-ray diffraction study of strain-induced crystallization of hydrogenated nitrile-butadiene rubbers: Effect of crosslink density about?

The structure and the mechanical and thermal properties of a hydrogenated acrylonitrile-butadiene rubber (HNBR) with acrylonitrile content of 44 wt% and residual unsaturation content of 9% are investigated as a function of the crosslink density. The analysis is focused on specimens that have not been subjected to any prior deformation. All samples are amorphous at room temperature and show glass transition temperatures that increase with increasing crosslink density. The values of the Young's modulus of the vulcanized samples are three times higher than that of the non-vulcanized counterpart and tend to increase with increasing the crosslink density. The tensile strength increases with increasing crosslink density, whereas the deformation at break decreases. All samples are amorphous at low deformations and whereas the non-vulcanized and the weakly and medium crosslinked samples undergo strain-induced crystallization (SIC) above a critical value of deformation, the highly crosslinked samples show only faint SIC and rupture at deformations slightly higher than that at SIC onset. It is shown that the deformation at SIC onset for the crosslinked samples tends to increase with increasi

Who reads X-ray diffraction study of strain-induced crystallization of hydrogenated nitrile-butadiene rubbers: Effect of crosslink density?

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Author
Femina, Giuseppe (author);de Ballesteros, Odda Ruiz (author);Urciuoli, Gaia (author);van Duin, Martin (author);Gögelein, Christoph (author);Tammaro, Daniele (author);Sotta, Paul (author);Auriemma, Finizia (author)
Publisher
Elsevier BV
Published
2023
Language
EN
Field
Materials Science (Physical Sciences)

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