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Facile Reduction Method Synthesis of Defective MoO~2– x ~ Nanospheres Used for SERS Detection with High Chemical Enhancement by Yu Cao; Pei Liang; Qianmin Dong; Dan Wang; De Zhang; Lisha Tang; Le Wang; Shangzhong Jin; Dejiang Ni; Zhi Yu is a Chemistry article available to read on EtoBox.

What is Facile Reduction Method Synthesis of Defective MoO~2– x ~ Nanospheres Used for SERS Detection with High Chemical Enhancement about?

Recently, more and more attention has been given to a semiconductor oxide-based surface-enhanced Raman spectroscopy substrate for its great stability and biocompatibility. However, its poor SERS sensitivity limits the applications of semiconductor oxide SERS substrates. In this paper, we provide a facile reduction method to modulate oxygen vacancy concentrations in oxide SERS substrates. Using MoO 2 as an example, the resonance coupling as well as charge transfer between the semiconductor oxide SERS substrate and the target molecules were promoted for the reason of artificial oxygen vacancy embodied in the Raman signals being improved. By using the TEM, SEM, and XPS measurements, we confirmed that we successfully prepared defective MoO 2-x with a polycrystalline surface. MoO 2-x modulated oxygen vacancy treated with 6 wt % Li shows a very high detection sensitivity of 10 -8 M (4.79 ug/L) for R6G, and the intensity of the Raman signal was highly enhanced. Because of the existence of defective energy levels, resonance coupling, as well as charge transfer between semiconductor and molecules, was obviously promoted. More importantly, the method of modulating oxygen vacancy can be widel

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It is typically read by researchers, students, and practitioners in Chemistry.

Author
Yu Cao; Pei Liang; Qianmin Dong; Dan Wang; De Zhang; Lisha Tang; Le Wang; Shangzhong Jin; Dejiang Ni; Zhi Yu
Publisher
American Chemical Society (ACS)
Published
2019
Language
EN
Field
Chemistry (Physical Sciences)

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