Can I read Asymmetric Transfer Hydrogenation of Substituted--Keto Carbonitriles via Dynamic Kinetic Resolution on EtoBox?

Asymmetric Transfer Hydrogenation of Substituted--Keto Carbonitriles via Dynamic Kinetic Resolution is a nonfiction available to read on EtoBox.

What is Asymmetric Transfer Hydrogenation of Substituted--Keto Carbonitriles via Dynamic Kinetic Resolution about?

## S4 S5 1v O CN 2-benzoyl-3-methylbutanenitrile (1c) 7 : white solid, 1.72 g, 92% yield. 1 H NMR (400 MHz, Chloroform-d) δ 8. 03 -7.89 (m, 2H), 7.72 -7.61 (m, 1H), 7.59 -7.48 (m, 2H), 4.37 (dd, J = 5.4, 3.1 Hz, 1H), 2.56 -2.36 (m, 1H), 1.18 (dd, J = 6.8, 1.5 Hz, 3H), 1.10 (dd, J = 6.8, 2.8 Hz, 3H). 13 C NMR (101 MHz, Chloroform-d) δ 191.2, 134.3, 129.0, 128.5, 116.1, 47.8, 29.8, 21.3, 18.6, 18.6. HRMS (ESI-TOF) m/z: [M+Na] + Calcd for C 12 H 13 NNaO + = 210.0889; Found 210.0887. O CN 2-benzoyl-4-methylpentanenitrile (1d) 7 : colorless oil, 1.81 g, 90% yield. 1 H NMR (400 MHz, Chloroform-d) δ 8.05 -7.93 (m, 2H), 7.73 -7.61 (m, 1H), 7.61 -7.47 (m, 2H), 4.43 (dd, J = 9.8, 5.2 Hz, 1H), 2.00 -1.88 (m, 2H), 1.85 -1.73 (m, 1H), 1.02 (dd, J = 14.4, 6.3 Hz, 6H). 13 C NMR (101 MHz, Chloroform-d) δ 191. 0, 134.3, 133.8, 129.0, 128.6, 117.3, 38.4, 38.3, 26.3, 22.6, 21.2. HRMS (ESI-TOF) m/z: [M+H] + Calcd for C 13 H 16 NO + = 202.1226; Found 202.1227. O CN Bn 2-benzoyl-4-phenylbutanenitrile (1e) 7 : white solid, 2.20 g, 88% yield. 1 H NMR (400 MHz, Chloroform-d) δ 7.99 -7.92 (m, 2H), 7.69 -7.60 (m, 1H), 7.55 -7.47 (m, 2H), 7.39 -7.26 (m, 5H), 4.58 -4.47 (m, 1H), 3.44 -3.17 (m, 2H). 13 C NMR (1

Who reads Asymmetric Transfer Hydrogenation of Substituted--Keto Carbonitriles via Dynamic Kinetic Resolution?

Publisher

American Chemical Society (ACS)

Language

EN

Category

nonfiction