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Semicarbazone and thiosemicarbazone appended 4-diethylamino-2‐hydroxybenzyl compounds as highly selective bifunctional chemosensors: An experimental and computational approach by Sethu Amuthakala; Sundaram Bharathi; Aziz Kalilur Rahiman is a Chemistry article available to read on EtoBox.

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Three bifunctional chemosensors, 2-(4-(diethylamino)-2-hydroxybenzylidene)hydrazinecarboxamide (S1), 2-(4-(diethylamino)-2-hydroxybenzylidene)hydrazinecarbothioamide (S2) and 2-(4-(diethylamino)-2-hydroxybenzylidene)-N-methylhydrazinecarbothioamide (S3) have been designed and synthesized for recognition of inorganic cations and anions in solution at room temperature. The structure of the receptor S2 was confirmed by single crystal X-ray diffraction technique, which crystallizes in the monoclinic P21/n space group. The selectivity and sensitivity of cations (Mn2+, Fe2+, Co2+, Ni2+, Cu2+, Zn2+ and Pb2+) and anions (F−, Cl−, Br−, I−, HSO4 − and H2PO4 −) were investigated using colorimetric, UV–vis absorption, emission and 1H NMR studies. The receptors (S1–S3) with ONO/ONS donors allow bare-face recognition of Co2+, Ni2+ and Cu2+ cations, and F− anion in a mixture of solvent, CH3CN:CH3OH (8:2, v/v). The receptor S3 possesses high sensitivity and selectivity in comparison with the receptors S1 and S2. The binding constant and limit of detection of the receptors with sensed cations and anion showed high sensitivity and selectivity towards Co2+ cation with order of magnitude 6, greater th

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Author

Sethu Amuthakala; Sundaram Bharathi; Aziz Kalilur Rahiman

Publisher

Elsevier BV

Published

2023

Language

EN

Field

Chemistry (Physical Sciences)