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Decarbonylation Kinetics of Formic Acid in Aqueous Sulphuric Acid Solutions by Dr. G. Ciuhandu; Dr. A. Dumitreanu; Dr. Z. Simon is a Chemistry article available to read on EtoBox.
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## Abstract Decarbonylation of formic acid in 46.6–80.2% (6.5–14.1 m) sulphuric acid was studied by driving CO out of the reaction medium by an air current followed by its photometrical determination with Ag‐Na‐sulphamoyl‐benzoate. The logarithm of the reaction rate constant increases straight with the acidity of the medium in the 6.5–12.6 M H~2~SO~4~ range. The data obtained argue in favour of a possible implication of a sulphuric acid molecule respectively hydrogensulphate ion in a rate controlling step.
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- Author
- Dr. G. Ciuhandu; Dr. A. Dumitreanu; Dr. Z. Simon
- Publisher
- John Wiley and Sons; Wiley (John Wiley & Sons); John Wiley & Sons Ltd.; Wiley - V C H Verlag GmbbH & Co.; Wiley (ISSN 1615-4150)
- Published
- 1976
- Language
- EN
- Field
- Chemistry (Physical Sciences)