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Bis(diphenyl­methyl­phosphine-κP)(disulfurdinitrido-κ2N,S)platinum(II) dichloro­methane solvate by Read, Benjamin D. ;Slawin, Alexandra M. Z. ;Woollins, J. Derek is a Chemistry article available to read on EtoBox.

What is Bis(diphenyl­methyl­phosphine-κP)(disulfurdinitrido-κ2N,S)platinum(II) dichloro­methane solvate about?

The title compound, [Pt(N~2~S~2~)(C~13~H~13~P)~2~]·CH~2~Cl~2~, contains Pt^II^ in a square-planar coordination. The five-membered PtS~2~N~2~ ring contains two short and one long S—N bonds. Interestingly, the S—N bond lengths have a different pattern from those in the PMe~2~Ph analogue and one of the published PPh~3~ analogues, but are comparable with those in most other systems containing the disulfurdinitride anion.

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Author

Read, Benjamin D. ;Slawin, Alexandra M. Z. ;Woollins, J. Derek

Publisher

International Union of Crystallography; Chester UK: International Union of Crystallography, 2001-2014.; [S.l.]: Wiley-Blackwell; [Chester]: 2008-; International Union of Crystallography (IUCr) (ISSN 1600-5368)

Published

2007

Language

EN

Field

Chemistry (Physical Sciences)