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Spectroscopic and crystal structure data of the alkali-, thallium (I) and onic-salts of dimethyl-N-trichloracetylamidophosphate by Victor A. Trush; Katerina E. Gubina; Vladimir M. Amirkhanov; Jolanta Swiatek-Kozlowska; Konstantin V. Domasevitch is a Chemistry article available to read on EtoBox.
What is Spectroscopic and crystal structure data of the alkali-, thallium (I) and onic-salts of dimethyl-N-trichloracetylamidophosphate about?
Alkali-, thallium (I) and onic-salts of dimethyl-N-trichloracetylamidophosphate [HL] were synthesized from non-aqueous solutions and characterized by means of X-ray diffraction, IR and 1 H NMR spectroscopy. An ionic type of metal-ligand interaction was determined in Na [L] (1), Rb [L] (2) and Tl [L] (3). Several compounds containing the tetraphenylphosphonium cation, such as PPh 4 [L] (4), (PPh 4 ) 2 [L]Br AE H 2 O ( ) and (PPh 4 ) 2 [Na 4 L 6 ] (6), were obtained by an exchange reaction between PPh 4 Br and (1) in different molar ratios. Compound 6 may be considered as the first example of an anionic complex of an alkali element in the coordination chemistry of carbacylamidophosphates. Synthesis and investigation of [SbPh 4 L] (7) allowed the determination of the preferable donor center of the L À ligand (the oxygen atom of the phosphoryl group).
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- Author
- Victor A. Trush; Katerina E. Gubina; Vladimir M. Amirkhanov; Jolanta Swiatek-Kozlowska; Konstantin V. Domasevitch
- Publisher
- Elsevier Science; Elsevier ; Elsevier Ltd.; Elsevier BV (ISSN 0277-5387)
- Published
- 2005
- Language
- EN
- Field
- Chemistry (Physical Sciences)